THERMAL-DECOMPOSITION KINETICS OF SOLID IRON(III) TRIS-N-P-NITROBENZOYL-N-PHENYLHYDROXYLAMINE

被引:4
|
作者
YOSHIDA, MI [1 ]
BRAGA, MM [1 ]
MACHADO, JC [1 ]
机构
[1] UFMG,ICEX,DEPT QUIM,CP 702,BR-31270901 BELO HORIZONT,MG,BRAZIL
关键词
D O I
10.1016/0040-6031(94)80192-4
中图分类号
O414.1 [热力学];
学科分类号
摘要
The thermal decomposition kinetics of iron(III) tris-N-p-nitrobenzoyl-N-phenylhydroxylamine was studied by the isothermal heating technique in the range 164-177-degrees-C. The principal non-gaseous stable products of the thermal decomposition were isolated and identified. The thermal decomposition process seems not to obey a single kinetic model in the full range of studied temperatures. Kinetic models that should account for the experimental evidence are discussed.
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页码:347 / 355
页数:9
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