INVESTIGATION OF THE ADDITION OF THIOLS TO POLYBUTADIENES

被引：20
|
作者：
KLEMM, E
GORSKI, U
机构：
来源：
ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1993年 / 207卷
关键词：
D O I：
10.1002/apmc.1993.052070117
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The free-radical addition of 1-octanediol (RSH) on polybutadienes with different molecular weights and configuration of the C-C double bonds occurs selectively to the 1,2-vinyl and 1,4-cis double bond, while the 1,4-trans double bond remains unchanged. The reactivity order 1,2- > cis > trans is confirmed by the model experiments with the isomers of pentene. The addition is favoured by the formation of an olefin/RSH charge-transfer complex as preinitiation step.
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页码：187 / 193
页数：7
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