Measurement and Correlation of Densities and Excess Volumes for Water

In this study, densities of water + N-Methyldiethanolamine (MDEA), Water + 2-Amino-2-Methyl-1-Propanol (AMP), MDEA + AMP binary systems and Water+MDEA+AMP ternary system were measured over the full range of composition at temperatures from 303.15 K to 333.15 K by using an Anton Paar digital vibrating tube densimeter (DMA4500). The experimental excess volumes have been obtained from the experimental density results and have been fitted using the Redlich-Kister-Muggianu expression. The parameters obtained from the binary excess volume data were used for the correlation of ternary system with one additional ternary parameter for each isotherm. All investigated binary and ternary systems are completely miscible, because the values of excess volume are negative under the examined conditions.