FORMATION OF CYCLIC CARBONATES IN THE REACTIONS OF 1,2-GLYCOLS WITH OXALYL CHLORIDE

被引：0

作者：

ITAYA, T

IIDA, T

EGUCHI, H

机构：

来源：

CHEMICAL & PHARMACEUTICAL BULLETIN | 1993年 / 41卷 / 02期

关键词：

OXALYL CHLORIDE DECARBONYLATION; 1,2-GLYCOL; 1,3-DIOXOLAN-2-ONE; 1,4-DIOXANE-2,3-DIONE; STEREOELECTRONIC EFFECT; TETRAHEDRAL INTERMEDIATE CLEAVAGE;

D O I：

暂无

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

Oxalyl chloride reacts with a wide range of 1,2-glycols in the presence of triethylamine to produce 1,3-dioxolan-2-ones together with 1,4-dioxane-2,3-diones; the ratio of the products largely depends on the structure of the 1,2-glycol. The formation or the cyclic carbonates may be rationalized in terms of stereoelectronically controlled cleavage of the tetrahedral intermediates.

引用

页码：408 / 410

页数：3

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