MECHANISTIC STUDY OF PHOTOELECTROCHEMICAL REACTIONS - PHOTO-TRANSIENT CHARACTERIZATION OF CE PROCESSES

被引：2
|
作者：
COMPTON, RG
EKLUND, JC
REBBITT, TO
机构：
[1] Physical Chemistry Laboratory, Oxford University, Oxford, OX1 3QZ, South Parks Road
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1995年 / 385卷 / 02期
基金：
英国工程与自然科学研究理事会;
关键词：
REACTION MECHANISMS;
D O I：
10.1016/0022-0728(94)03766-V
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A channel electrode photo-transient experiment is described for the mechanistic characterization of photo-CE processes. This involves monitoring the transport limited current due to the discharge of a photo-generated electroactive species immediately following the stepwise application of light to the system. The theory of the experiment is given and a working surface presented which allows the analysis of experimental transients regardless of the cell geometry or solution flow rate used in their measurement. The approach is applied to the photo-electrochemical oxidation of the aminocarbene complex [(eta(5)-C5H5)Fe(CO){P(p-Tol)(3)}{=C(NHMe)(Me)}]BF4 in acetonitrile solution at a platinum electrode. The process, in the presence of light of wavelengths near 330 nm, is confirmed to be of the photo-CE type.
引用
收藏
页码：143 / 147
页数：5
相关论文
共 19 条
12