REACTIONS OF THE DIRHENIUM(II) COMPLEXES [RE2X4(DPPM)2] (X = CL OR BR, DPPM = PH2PCH2PPH2) WITH ISOCYANIDES .2. THE A-FRAME-LIKE MONOISOCYANIDE SPECIES [RE2(MU-X)(MU-DPPM)2X3(CNR)]N+ (R = ME, BUT, OR C6H3ME2-2,6,N = 0 OR 1)

被引：18

作者：

ANDERSON, LB

BARDER, TJ

ESJORNSON, D

WALTON, RA

BURSTEN, BE

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

[2] OHIO STATE UNIV,DEPT CHEM,COLUMBUS,OH 43210

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1986年 / 12期

关键词：

D O I：

10.1039/dt9860002607

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：2607 / 2612

页数：6

共 50 条

[1] Reactions of the dirhenium(II) complexes Re2X4(μ-dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with isocyanides -: Part XX.: Oxidation of the complexes Re2X4(μ-dppm)2(L) (X = Cl or Br; dppm = Ph2PCH2PPh2; L = t-BuNC, XylNC or CO) to the edge-sharing bioctahedral dirhenium(III) cations [Re2(μ-X)2(μ-dppm)2X3(L)]+
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[2] REACTIONS OF THE DIRHENIUM(II) COMPLEXES RE(2)X(4)(DPPM)(2) (X=CL,BR, DPPM=PH(2)PCH(2)PPH(2)) WITH ISOCYANIDES .7. MONOCARBONYL COMPLEXES OF THE TYPE RE(2)X(4)(MU-DPPM)(2)(CO) (X=CL,BR, DPPM=PH(2)PCH(2)PPH(2)) REVISITED - REACTIONS OF THE BROMO COMPLEX RE2BR4(MU-DPPM)(2)(CO) WITH TERT-BUTYL AND XYLYL ISOCYANIDES
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[4] CARBONYLATION OF THE TRIPLY BONDED DIRHENIUM(II) COMPLEXES RE2X4(DPPM)2(X=CL,BR - DPPM=PH2PCH2PPH2 TO GIVE [RE2X3(DPPM)2(CO)2]PF6 - STRUCTURAL CHARACTERIZATION OF [(CO)CIRE(MU-CL)(MU-CO)(MU-DPPM)2RECL(CO)]PF6
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[5] OXIDATIVE ADDITION OF DIPHENYLPHOSPHINE TO THE ELECTRON-RICH TRIPLE BOND OF RE2X4(MU-DPPM)2 (X = CL OR BR DPPM = PH2PCH2PPH2)
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[6] STRUCTURAL ISOMERS OF THE TRIPLY BONDED COMPLEXES RE2X2(MU-O2CR)2(MU-DPPM)2 (X = CL, BR, R = ME, ET, PH, DPPM = PH2PCH2PPH2)
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[7] Reactions of the dirhenium(II) complexes Re2X4(mu-dppm)(2) (X=Cl, Br; dppm=Ph2PCH2PPh2) with isocyanides .13. Identification of a new structural isomer of the dirhenium cation [Re2Cl3(mu-dppm)(2)(CO)(CNXyl)(2)](+) and its isomerization behavior. Structural characterization of (XylNC)ClRe(mu-Cl)(mu-CNXyl)(mu-dppm)(2)ReCl(CO)
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