REACTIONS OF 1, 1'-DIALKYNYLFERROCENE WITH OCTACARBONYLDICOBALT

被引：2

作者：

ONITSUKA, K ^{[1
]}

TAO, XQ ^{[1
]}

OTSUKA, Y ^{[1
]}

SONOGASHIRA, K ^{[1
]}

机构：

[1] OSAKA CITY UNIV, FAC ENGN, DEPT APPL CHEM, SUMIYOSHI KU, OSAKA 558, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 08期

关键词：

D O I：

10.1246/cl.1993.1353

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 1, l'-dialkynylferrocene (eta5-C5H4C=CR)2Fe (1) (R=Ph, SiMe3, Me, Fc; Fc=ferrocenyl) with excess octacarbonyldicobalt (2) results in the formation of dark green complexes (eta5-C5H4C-CR)2Fe{Co2(CO)6}2 (3) (R=Ph, SiMe3, Me, Fc), in which a Co2(CO)6 group coordinates to each of the two C-C bonds of 1. When 1, 1'-di(phenylethynyl)ferrocene (1a) was treated with an equimolar amount of 2, (eta5-C5H4C=CPh)2Fe{Co2(CO)6), as well as 3a, was obtained.

引用

页码：1353 / 1356

页数：4

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