MAGNETIC-PROPERTIES IN THE SERIES TLXV6-YMYS8 (M = CR, MN, FE, 0 LESS-THAN-OR-EQUAL-TO Y LESS-THAN-OR-EQUAL-TO 1)

被引:9
|
作者
BENSCH, W
ABART, J
AMBERGER, E
机构
[1] SIEMENS AG,VB MED,D-8520 ERLANGEN,FED REP GER
[2] INST ANORGAN CHEM,D-8000 MUNCHEN 2,FED REP GER
关键词
METALS AND ALLOYS;
D O I
10.1016/0038-1098(86)90235-8
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Ternary vanadium sulfides with various 3d transition metal substitutes were prepared by thermal treatment and characterized by X-ray diffraction. Magnetic susceptibility measurements on the homogeneous powders reveal that itinerant and localized magnetism in all samples coexists, due to different ionic charges. The localized magnetic behavior increases in the direction of the late 3d elements. With Mossbauer spectroscopy a Fe**2** plus in the high spin state is found. The magnetic behavior of the series is discussed.
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页码:631 / 635
页数:5
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