SYNTHESIS AND CRYSTAL-STRUCTURE OF [MNII(H3L)(L)MNIV][PF6]3 [H3L = N,N',N''-TRIS-(2S)-2-HYDROXYPROPYL-1,4,7-TRIAZACYCLONONANE] - A MIXED-VALENCE PENDANT-ARM MACROCYCLE DIMER IN WHICH THE LIGAND ADOPTS DIFFERENT ANGULAR GEOMETRIES AT THE 2 METAL CENTERS

被引：20

作者：

BELAL, AA ^{[1
]}

FALLIS, I ^{[1
]}

FARRUGIA, LJ ^{[1
]}

MACDONALD, NM ^{[1
]}

PEACOCK, RD ^{[1
]}

机构：

[1] UNIV GLASGOW,DEPT CHEM,GLASGOW G12 8QQ,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 06期

关键词：

D O I：

10.1039/c39910000402

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of N,N',N''-tris(2S)-2-hydroxypropyl-1,4,7-triazacyclononane (H3L) with MnCl2 in neutral or slightly basic conditions affords (Mn(II)(H3L)(L)Mn(IV)][PF6]3, a mixed-valence, hydrogen-bridged dimer in which the Mn(IV) half has pseudooctahedral geometry and the Mn(II) half has trigonal prismatic geometry.

引用

页码：402 / 403

页数：2

共 48 条

[1] SYNTHESIS AND SPECTROSCOPIC STUDIES OF COBALT(III) COMPLEXES OF THE CHIRAL PENDANT-ARM MACROCYCLE N,N',N''-TRIS[(2S)-2-HYDROXYPROPYL]-1,4,7-TRIAZACYCLONONANE (H3L) - CRYSTAL-STRUCTURE OF THE HYDROGEN-BRIDGED DIMER [COLH3LCO][PF6]3
BELAL, AA
FARRUGIA, LJ
PEACOCK, RD
ROBB, J
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (05): : 931 - 935
[2] SYNTHESIS AND CRYSTAL-STRUCTURE OF [ZN(II)(LH3)(L)V(IV)][PF6]3[LH3 = N,N',N''-TRIS(2S)-2-HYDROXYPROPYL-1,4,7-TRIAZACYCLONONANE] - A CHIRAL MIXED-METAL PENDANT-ARM MACROCYCLIC DIMER CONTAINING NON-VANADYL VANADIUM(IV)
FALLIS, I
FARRUGIA, LJ
MACDONALD, NM
PEACOCK, RD
INORGANIC CHEMISTRY, 1993, 32 (06) : 779 - 780
[3] Experimental determination of the electron density topology in a non-centrosymmetric transition metal complex: [Ni(H3L)][NO3][PF6] [H3L=N,N',N''-tris(2-hydroxy-3-methylbutyl)-1,4,7-triazacyclononane]
Smith, GT
Mallinson, PR
Frampton, CS
Farrugia, LJ
Peacock, RD
Howard, JAK
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (21) : 5028 - 5034
[4] SYNTHESIS, X-RAY CRYSTAL-STRUCTURE AND SPECTROSCOPY OF THE HYDROGEN-BRIDGED DIMER [CR-III(L-CENTER-DOT-H(3)L)CR-III][PF6](3) (H(3)L=N,N',N''-TRIS[(2S)-2-HYDROXYPROPYL]-1,4,7-TRIAZACYCLONONANE)
FARRUGIA, LJ
MACDONALD, NM
PEACOCK, RD
ROBB, J
POLYHEDRON, 1995, 14 (04) : 541 - 545
[5] Experimental charge-density study on the nickel(II) coordination complex [Ni(H3L)][NO3][PF6] [H3L = N,N′,N″-tris(2-hydroxy-3-methylbutyl)-1/4,7-triazacyclononane]: A reappraisal
WestCHEM, Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, United Kingdom
不详
Acta Crystallogr. Sect. B Struct. Sci., 2006, 2 (236-244):
[6] Experimental charge-density study on the nickel(II) coordination complex [Ni(H3L)] [NO3][PF6][H3L = N,N′,N"-tris(2-hydroxy-3-methylbutyl)-1,4,7-triaza-cyclononane]:: a reappraisal
Farrugia, LJ
Frampton, CS
Howard, JAK
Mallinson, PR
Peacock, RD
Smith, GT
Stewart, B
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2006, 62 : 236 - 244
[7] Experimental charge-density study on the nickel(II) coordination complex [Ni(H3L)][NO3][PF6] [H3L = N,N′,N″-tris(2-hydroxy-3-methylbutyl)-1,4,7-triaza-cyclononane]: A reappraisal
WestCHEM, Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, United Kingdom
不详
Electrochem Solid State Letters, 2006, 5 (236-244):
[8] SYNTHESIS AND STRUCTURAL AND SPECTROSCOPIC STUDIES OF MANGANESE COMPLEXES OF PENDANT-ARM MACROCYCLES BASED ON 1,4,7-TRIAZACYCLONONANE - CRYSTAL-STRUCTURES OF THE MANGANESE(II) COMPLEX [MNLH3][MNCL4] AND OF THE MIXED-VALENCE MANGANESE(II)-MANGANESE(IV) HYDROGEN-BRIDGED DIMER [MNLH3LMN][PF6]3(LH3=N,N',N''-TRIS[(2S)-2-HYDROXYPROPYL]-1,4,7-TRIAZACYCLONONANE), AND OF THE MANGANESE(IV) MONOMER [MNL'][CLO4](L'H3=N,N',N''-TRIS(2-HYDROXYETHYL)-1,4,7-TRIAZACYCLONONANE)
BELAL, AA
CHAUDHURI, P
FALLIS, I
FARRUGIA, LJ
HARTUNG, R
MACDONALD, NM
NUBER, B
PEACOCK, RD
WEISS, J
WIEGHARDT, K
INORGANIC CHEMISTRY, 1991, 30 (23) : 4397 - 4402
[9] Synthesis and crystal structure of an azido-bridged cadmium(II) dimer [L2Cd2(μ-N3)2(N3)2] (L=1,4,7-triazacyclononane)
Gu, W
Xie, CZ
Bian, HD
Chen, P
Yan, SP
Liao, DZ
Jiang, ZH
JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (05) : 427 - 431
[10] THE NOVEL MIXED-VALENCE, EXCHANGE-COUPLED, CLASS-III DIMER [L2FE2(MU-OH)3]2+ (L = N,N',N''-TRIMETHYL-1,4,7-TRIAZACYCLONONANE)
DRUEKE, S
CHAUDHURI, P
POHL, K
WIEGHARDT, K
DING, XQ
BILL, E
SAWARYN, A
TRAUTWEIN, AX
WINKLER, H
GURMAN, SJ
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (01) : 59 - 62

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