A SIMPLE METHOD FOR ESTIMATING ACTIVATION-ENERGY FROM DERIVATIVE THERMOANALYTICAL CURVES AND ITS APPLICATION TO THERMAL SHRINKAGE OF POLYCARBONAYE

被引：18

作者：

OZAWA, T ^{[1
]}

KATO, T ^{[1
]}

机构：

[1] UNIV UTSUNOMIYA,FAC ENGN,DEPT APPL CHEM,UTSUNOMIYA 321,JAPAN

来源：

JOURNAL OF THERMAL ANALYSIS | 1991年 / 37卷 / 06期

关键词：

D O I：

10.1007/BF01913863

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Activation energy can be estimated by a new simple method, in which logarithm of maximum rate of conversion observed at different heating rates is plotted against reciprocal absolute temperature, because the conversion at the maximum rate is approximately independent of the heating rate. The method is applied to thermal shrinkage of polycarbonate, and the estimated activation energy is in good agreement with those obtained by conventional methods.

引用

页码：1299 / 1307

页数：9

共 5 条

[1] ESTIMATION OF ACTIVATION-ENERGY ON BASIS OF THERMAL CURVES BY OZAWAS METHOD
ORSI, F
PERIODICA POLYTECHNICA-CHEMICAL ENGINEERING, 1975, 19 (04) : 281 - 289
[2] DETERMINATION OF ACTIVATION-ENERGY OF THERMAL POLYMERIZATION OF ACROLEIN FROM THERMOKINETIC CURVES
KHARDIN, AP
VALDMAN, DI
DERBISHER, VE
PANFILOV, BI
BUKALOV, VI
VALDMAN, AI
JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1976, 49 (11): : 2564 - 2567
[3] DETERMINATION OF ACTIVATION-ENERGY FOR THERMAL REGENERATION OF EL2 FROM ITS METASTABLE STATE BY THERMALLY STIMULATED PHOTOCURRENT MEASUREMENTS
MOHAPATRA, YN
KUMAR, V
JOURNAL OF APPLIED PHYSICS, 1988, 64 (02) : 956 - 958
[4] A simple method for fast temperature changes and its application to thermal activation of TRPV1 ion channels
Islas, Leon D.
De-la-Rosa, Victor
Rodriguez-Cortes, Beatriz
Rangel-Yescas, Gisela E.
Elias-Vinas, David
JOURNAL OF NEUROSCIENCE METHODS, 2015, 243 : 120 - 125
[5] A NEW AND SIMPLE METHOD TO ESTIMATE F(E) AND K(0)(E) IN THE DISTRIBUTED ACTIVATION-ENERGY MODEL FROM 3 SETS OF EXPERIMENTAL-DATA
MIURA, K
ENERGY & FUELS, 1995, 9 (02) : 302 - 307

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