PREPARATION OF ULTRATHIN FILMS OF AROMATIC POLYAMIDES AND AROMATIC POLY(AMIDE IMIDES) BY VAPOR-DEPOSITION POLYMERIZATION

被引：42
|
作者：
TAKAHASHI, Y
IIJIMA, M
OISHI, Y
KAKIMOTO, M
IMAI, Y
机构：
[1] TOKYO INST TECHNOL,DEPT ORGAN & POLYMER MAT,MEGURO KU,TOKYO 152,JAPAN
[2] ULVAC JAPAN LTD,INST SUPER MAT,TSUKUBA,IBARAKI 30026,JAPAN
来源：
MACROMOLECULES | 1991年 / 24卷 / 12期
关键词：
D O I：
10.1021/ma00012a013
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Ultrathin films of aromatic polyamides and aromatic poly(amide-imides) were prepared by vapor deposition polymerization. Terephthaloyl chloride and some aromatic diamines were evaporated under reduced pressure, giving polyamide films directly on a substrate. The evaporation of 4-(chloroformyl)phthalic anhydride together with aromatic diamines afforded films of poly(amide-amic acids), which in turn were converted to poly(amide-imides) by heat treatment. The thermal stability, chemical inertness, and dielectric properties of these polymer films were comparable with those of polymer films obtained by a conventional solution method.
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收藏
页码：3543 / 3546
页数：4
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