SYNTHESIS AND CHARACTERIZATION OF NONAISOPROPOXODIZIRCONATOTIN(IV) COMPLEXES

被引：0

作者：

MATHUR, S ^{[1
]}

SINGH, A ^{[1
]}

MEHROTRA, RC ^{[1
]}

机构：

[1] UNIV RAJASTHAN,DEPT CHEM,JAIPUR 302004,RAJASTHAN,INDIA

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1995年 / 34卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A number of novel heteroleptic nonaisopropoxodizirconatotin(IV) complexes of the type [Sn{Zr-2(OPri)(9)}Cl-n(4-n)] (where n=1-3) have been synthesised by the reactions of SnCl4 with KZr2(OPri)(9), in benzene in requisite (1:1, 1:2, or 1:3) molar ratios. Replacement df chloride in these derivatives by an appropriate alkoxide affords volatile, heterobimetallic derivatives of the type [Sn{Zr-2(OPri)(9)}(n)(OR)(4-n)] (R=Pr-i, Bu(t), n=2 or 3). These novel heterometal alkoxides have been characterized by elemental analyses,molecular weight measurements, IR and multinuclear (H-1, C-13 and Sn-119) NMR spectral studies.

引用

页码：454 / 458

页数：5

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