HIGH-NUCLEARITY CLUSTERS

被引：18
|
作者：
JOHNSON, BFG [1 ]
LEWIS, J [1 ]
GALLUP, M [1 ]
MARTINELLI, M [1 ]
机构：
[1] UNIV CAMBRIDGE, CHEM LAB, CAMBRIDGE CB2 1EW, ENGLAND
来源：
FARADAY DISCUSSIONS | 1991年 / 92卷
关键词：
D O I：
10.1039/fd9919200241
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The use of discrete metal cluster compounds as models of chemisorption systems in surface chemistry is described. Possible boundary conditions to such a cluster-surface analogy are examined; drawing extensively on the interfacial chemistry of benzene. in particular, the complex [Os3(CO)9(mu-3-C6H6)], which contains benzene in an important new face-capping bonding mode that accurately models benzene adsorption at a three-fold site on the surface of a close-packed metal lattice will be described and its chemistry discussed.
引用
收藏
页码：241 / 254
页数：14
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