SYNTHESIS AND CHARACTERIZATION OF MU-CYANO(OCTAETHYLPORPHYRINATO)COBALT(III)

被引：4

作者：

FAHMY, N

LEVERENZ, A

HANACK, M

机构：

[1] Institut für Organische Chemie, D-7400 Tübingen

来源：

SYNTHETIC METALS | 1991年 / 42卷 / 03期

关键词：

D O I：

10.1016/0379-6779(91)91436-E

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Mu-(Octaethylporphyrinato)cobalt(II), OEpCo (1), reacts with sodium cyanide and simultaneous oxidation with air oxygen to form sodium dicyano(octaethylporphyrinato)cobalt(III), Na[OEPCo(CN)2] (2), which is converted into mu-cyano(octaethylporphyrinato)cobalt(III), [OEPCoCN]n (3), in aqueous medium. Treatment of the oligomer 3 with pyridine leads to the monomeric complex OEPCoCN(py) (4). Intermediate products arising at the electrode during electrochemical oxidation and reduction of 1, 2 and 3 were analysed with spectroelectrochemical techniques.

引用

页码：2615 / 2619

页数：5

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