ION MOLECULE REACTIONS OF NUCLEAR-CHEMICAL GENERATED PHENYL CATIONS WITH HALOBENZENES

被引：0
|
作者：
NEFEDOV, VD
TOROPOVA, MA
SHCHEPINA, NE
AVRORIN, VV
ROMERO, AM
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来源：
SOVIET RADIOCHEMISTRY | 1992年 / 34卷 / 04期
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中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Ion-molecule reactions of phenyl cations generated through beta-decay of H-3 in multiply tritiated-benzene with halobenzenes except fluorobenzene are studied. The results are consistent with competing reactions of phenyl cations with both the unshared electron pair of the halogen as p-centers of the substrate (to form H-3-labelled diphenylhalonium salts and halobenzenes) and the pi-system of the benzene ring (to give halobiphenyl isomers).
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页码：484 / 487
页数：4
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