SYNTHESIS OF A PHEROMONE OF BOARMIA-SELENARIA VIA A SILA-COPE ELIMINATION - STEREOCHEMICAL IMPLICATIONS

被引：8
|
作者：
LANGLOIS, Y
KONOPSKI, L
BAC, NV
CHIARONI, A
RICHE, C
机构：
[1] Institut de Chimie des Substances Naturelles, C.N.R.S.
来源：
TETRAHEDRON LETTERS | 1990年 / 31卷 / 13期
关键词：
D O I：
10.1016/S0040-4039(00)98806-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The use of a Sila-Cope elimination afforded aZ,Z,Z trienamine derivative, direct synthetic precursor of (3Z,6Z,9Z)-3,6,9-nonadecatriene1, one of the pheromone components ofBoarmia selenaria. X-ray analysis of the tetrahydropyridinium salt13 leading to the dienic Vinyl silane14 allowed the determination of the relative configurations of the tetrahydropyridine intermediates7,8,9 and12. © 1990 Pergamon Press plc.
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页码：1865 / 1868
页数：4
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