HIGHLY REGIOSELECTIVE TIN-MEDIATED RING-OPENING OF 2,3-EPOXY ALCOHOL DERIVATIVES WITH TRIMETHYLSILYL HALIDE

被引：0
|
作者：
ORIYAMA, T
ISHIWATA, A
HORI, Y
YATABE, T
HASUMI, N
KOGA, G
机构：
来源：
SYNLETT | 1995年 / 10期
关键词：
RING-OPENING; 2,3-EPOXY ALCOHOL; REGIOSELECTIVE TIN(II) HALIDE; TRIMETHYLSILYL HALIDE;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The oxirane ring of 2,3-epoxy alcohol derivatives are shown to be cleaved regioselectively at C-3-O to give O-acetylated vicinal halohydrins when reacted with trimethylsilyl halide in the presence of tin(II) halide as a catalyst followed by treatment with acetyl halide.
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页码：1004 / &
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