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OXYGEN PARTITIONING ANALYSIS DURING CZOCHRALSKI SILICON CRYSTAL-GROWTH VIA A DOPANT MARKER AND A SIMPLE TRANSFER-FUNCTION MODELING TECHNIQUE .2. GROWTH VELOCITY AND APPLIED MAGNETIC-FIELD TRANSIENTS
被引:6
|作者:
YEN, CT
TILLER, WA
机构:
[1] Department of Materials Science and Engineering, Stanford University, Stanford
关键词:
D O I:
10.1016/0022-0248(92)90052-K
中图分类号:
O7 [晶体学];
学科分类号:
0702 ;
070205 ;
0703 ;
080501 ;
摘要:
Intermediate transient oxygen redistribution during commercial size scale Czochralski silicon crystal growth caused by a step change in crystal growth velocity and applied magnetic field has been examined using the dopant marker/transfer function modeling technique. A single oxygen species in the melt is unable to fit the experimental data. However, a model based upon two oxygen species, SiO4 tetrahedra and O monomer, with k0O > 1 and k0SiO4 << 1 plus a melt reaction, SiO4 <-> Si + 4O, is able to provide good fit to the data. Such a two oxygen species model yields an effective partition coefficient for oxygen greater than or less than unity depending upon the particular set of melt and crystal growth conditions.
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页码:85 / 92
页数:8
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