Tellurium-doped lanthanum manganite as catalysts for the oxygen reduction reaction

被引:0
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作者
V. Celorrio
L. J. Morris
M. Cattelan
N. A. Fox
D. J. Fermin
机构
[1] University of Bristol,School of Chemistry
[2] Cardiff University,EPSRC Centre for Doctoral Training in Catalysis, School of Chemistry
来源
MRS Communications | 2017年 / 7卷
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摘要
The effect of tellurium (Te) doping on the electrocatalytic activity of La1-xTexMnO3 toward the oxygen reduction reaction is investigated for the first time. La1-xTexMnO3 with x-values up 23% were synthesized from a single ionic liquid-based precursor, yielding nanoparticles with mean diameter in the range of 40–68 nm and rhombohedral unit cell. Electrochemical studies were performed on carbon-supported particles in alkaline environment. The composition dependence activity is discussed in terms of surface density of Mn sites and changes in the effective Mn oxidation state.
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页码:193 / 198
页数:5
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