Oxidative polymerization of pyrrole in the presence of a poly (sodium-p-styrenesulfonate) and its gas-responses

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作者
Xingfa Ma
Guang Li
Mang Wang
Hongzheng Chen
机构
[1] Zhejiang University,Department of Polymer Science & Engineering, State Key Lab of Silicon Materials
[2] Zhejiang University,Institute of Biomedical and Instrument Science, State Key Lab of Biosensors
[3] Shandong Research Institute of Non-metallic Materials,undefined
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关键词
Pyrrole; Polypyrrole; Trimethylamine; Oxidative Polymerization; Film Sensor;
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摘要
To overcome the problem of film-forming technology, water-soluble polypyrrole was obtained in the process of chemical oxide by adding a small amount of poly (sodium-p-styrenesulfonate). The resulting product PPy/Poly(sodium-p-styrene sulfonat) was coated on the interdigital electrodes of carbon via spin-coating or casting approach, and its gas-sensitivity to trimethylamine at room temperature was investigated. The results indicated that, the technology of film-forming was not only improved greatly, but also this film still showed good gas-sensitivity to trimethylamine of 3.189 × 10−1 mol/m3, its value of gas-sensitivity had reached to 2–3 orders of magnitude within 3 min, had good selectivity to analogy gases, and its resistance to moisture was improved obviously. Otherwise, this film also exhibited good reproducibility and stability, and easily recovered with high-purity N2 at room temperature.
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页码:7604 / 7610
页数:6
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