Heavy lanthanide phosphates: Nanostructuring during their solid-phase synthesis

被引：0
|
作者：
G. A. Bandurkin
N. N. Chudinova
G. V. Lysanova
V. A. Krut’ko
K. K. Palkina
M. G. Komova
机构：
[1] Russian Academy of Sciences,Kumakov Institute of General and Inorganic Chemistry
来源：
Russian Journal of Inorganic Chemistry | 2006年 / 51卷
关键词：
Trigonal Prism; Anionic Component; Unit Layer; Lanthanide Phosphate; Vertex Sharing;
D O I：
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中图分类号：
学科分类号：
摘要：
Specific features of the textures (the preferred orientation of the nanometer building blocks) of the cationic and anionic components of the structures of phosphates forming in the Ln2O3-P2O5 systems (Ln = Er-Lu) have been studied. Nanostructuring upon the formation of phosphates is determined by two oppositely directed processes of fragmentation of corresponding infinite cationic and anionic frameworks to elementary blocks, LnOn polyhedra and [PO4] tetrahedra.
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页码：1473 / 1482
页数：9
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