N-Allyl-substituted aminomethylene-1,1-bisphosphonates in 1,3-dipolar cycloaddition reaction with aromatic nitrile N-oxides

被引：0
|
作者：
O. V. Bykhovskaya
I. M. Aladzheva
V. K. Brel
机构：
[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
来源：
Russian Chemical Bulletin | 2017年 / 66卷
关键词：
-allyl-substituted aminomethylene-1,1-bisphosphonates; 1,3-dipolar cycloaddition; 3-arylisoxazolines; diastereomers;
D O I：
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中图分类号：
学科分类号：
摘要：
A reaction of N-allyl-substituted aminomethylene-1,1-bisphosphonates with aromatic nitrile N-oxides was used to obtain new aminomethylenebisphosphonates with one or two 3-arylisoxazoline rings at the nitrogen atom. NMR spectroscopy studies showed that the bisphosphonates with two isoxazoline fragments in the molecule exist in solution as a mixture of two diastereomers.
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页码：1256 / 1260
页数：4
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