Anionic polymerization of N-substituted maleimide with achiral and chiral amines as an initiator

被引：0
|
作者：
Motohisa Azechi
Nami Toyota
Kazuhiro Yamabuki
Kenjiro Onimura
Tsutomu Oishi
机构：
[1] Yamaguchi University,Graduate School of Science and Engineering
来源：
Polymer Bulletin | 2011年 / 67卷
关键词：
Anionic polymerization; -Substituted maleimide; Amine; Optically active polymer;
D O I：
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中图分类号：
学科分类号：
摘要：
We have investigated anionic polymerization ability of N-substituted maleimides (RMI) with various amines as anionic initiator. As a result, anionic polymerizations of RMI proceed successfully in high polar solvents such as DMF and DMSO. The basicity and structure of amines influenced yields and number average molecular weights of polymers. Furthermore, using various chiral amines as an initiator, polymerizations of RMI were performed to obtain optically active polymers.
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页码：631 / 640
页数：9
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