Electrochemical characterization of carbon paste electrodes modified with MgZnGa and ZnGaAl hydrotalcite-like compounds

被引：0
|
作者：
Vianney Aguilar-Vargas
Jaime S. Valente
Ignacio González
机构：
[1] Universidad Autónoma Metropolitana,Departamento de Química
[2] Instituto Mexicano del Petróleo,undefined
来源：
Journal of Solid State Electrochemistry | 2013年 / 17卷
关键词：
Hydrotalcites; Carbon paste electrodes; Electrocatalysis; Chronoamperometry; Voltammetry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Two hydrotalcite-like compounds (HTs) were synthesized by coprecipitation. The electrochemical behavior of MgZnGa ([Mg0.58 Zn0.17Ga0.25 (OH)2] (CO3)2−0.125 1.5 H2O) and ZnGaAl ([Zn0.75Ga0.19 Al0.06 (OH)2] (CO3)2−0.125·1.5 H2O) Hydrotalcite-like compounds (HTs) was studied in NaOH at different concentrations. Voltammetric and chronoamperometric studies were performed to identify oxidation and reduction processes and the effect of the cations in total reactivity. Electrocatalytic effect of HTs on hydroxide electrochemical oxidation shows better performance of MgZnGa; this is apparently due to the presence of Mg and a greater amount of Ga3+ in the lattice of this HT. As far as reduction is concerned, Zn(II) reduction process is observed within the lattices of both HTs and is influenced by both the amount of OH− in the solution and the potential which the previous oxidation has been performed.
引用
收藏
页码：3145 / 3152
页数：7
相关论文
共 50 条
  • [1] Electrochemical characterization of carbon paste electrodes modified with MgZnGa and ZnGaAl hydrotalcite-like compounds
    Aguilar-Vargas, Vianney
    Valente, Jaime S.
    Gonzalez, Ignacio
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2013, 17 (12) : 3145 - 3152
  • [2] Electrochemical characterisation of electrodes modified with a Co/Al hydrotalcite-like compound
    Scavetta, E
    Berrettoni, M
    Nobili, F
    Tonelli, D
    ELECTROCHIMICA ACTA, 2005, 50 (16-17) : 3305 - 3311
  • [3] Characterization of surfactant/hydrotalcite-like clay/glassy carbon modified electrodes:: Oxidation of phenol
    Hernandez, Maria
    Fenandez, Lenys
    Borras, Carlos
    Mostany, Jorge
    Carrero, Hermes
    ANALYTICA CHIMICA ACTA, 2007, 597 (02) : 245 - 256
  • [4] Hydrotalcite-like compounds as adsorbents for carbon dioxide
    Yong, Z
    Rodrigues, AE
    ENERGY CONVERSION AND MANAGEMENT, 2002, 43 (14) : 1865 - 1876
  • [5] Preparation and characterization of CuMgAl hydrotalcite-like compounds
    Shen, Yanming
    Wu, Jing
    Tang, Yangjun
    Zhang, Hui
    Wang, Lei
    Liu, Changhou
    Zhang, Zhenxiang
    Kuei Suan Jen Hsueh Pao/ Journal of the Chinese Ceramic Society, 2009, 37 (02): : 285 - 290
  • [6] Characterization and Electrochemical Behaviour of Nanoscale Hydrotalcite-Like Compounds toward the Reduction of Nitrate
    Li, Liang
    Yang, Junhao
    Yun, Yafeng
    Hu, Shouxun
    Huang, Yuanxing
    NANOMATERIALS, 2020, 10 (10) : 1 - 16
  • [7] ELECTROCHEMICAL CHARACTERIZATION OF CARBON PASTE ELECTRODES MODIFIED WITH NATURAL ZEOLITE
    Zacahua Tlacuatl, G.
    Castro Arellano, J. J.
    Manzo-Robledo, A.
    CHEMICAL ENGINEERING COMMUNICATIONS, 2009, 196 (10) : 1178 - 1188
  • [8] Adsorption of carbon dioxide on hydrotalcite-like compounds of different compositions
    Aschenbrenner, Ortrud
    McGuire, Paul
    Alsamaq, Suzanne
    Wang, Jiawei
    Supasitmongkol, Somsak
    Al-Duri, Bushra
    Styring, Peter
    Wood, Joseph
    CHEMICAL ENGINEERING RESEARCH & DESIGN, 2011, 89 (09): : 1711 - 1721
  • [9] Synthesis and Structural Characterization of Mg/Al hydrotalcite-like compounds
    Guo, Yan
    Liu, Weijun
    Zhang, Shuhua
    Yang, Siyuan
    Zhang, Kaifei
    Liao, Jianjun
    CHEMICAL ENGINEERING AND MATERIAL PROPERTIES II, 2012, 549 : 353 - 357
  • [10] Synthesis and characterization of the mixed Mg/Al hydrotalcite-like compounds
    Li, Shu-Ping
    Zhou, Zhi-Ping
    JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2006, 27 (08) : 1079 - 1084
12345