Effect of CH4/air ratio on selectivity of partial oxidation of methane on V2O5/SiO2 catalyst

被引：0

作者：

Bostan A.I. ^{[1
]}

Pyatnitskii Yu.I. ^{[1
]}

Raevskaya L.N. ^{[1
]}

Borisenko M.V. ^{[2
]}

Pryanikova V.G. ^{[1
]}

机构：

[1] L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 03039 Kyiv

[2] Institute of Surface Chemistry, National Academy of Sciences of Ukraine, 03164 Kyiv

来源：

Theoretical and Experimental Chemistry | 2002年 / 38卷 / 6期

关键词：

Catalyst; Conversion; Formaldehyde; Methane; Partial oxidation; Selectivity;

D O I：

10.1023/A:1022223703187

中图分类号：

学科分类号：

摘要：

We have studied partial oxidation of methane on V2O 5/SiO2 (0.8 mass % V) in a flow-through catalytic fixed-bed reactor. We found that the methane/air ratio in the starting reaction mixture has practically no effect on the selectivity of the process. The dependence of the selectivity on the methane conversion can be described by a model with such reaction parameters as the initial selectivity and the relative reactivity (with respect to methane) of the reaction products. ©2002 Plenum Publishing Corporation.

引用

页码：363 / 366

页数：3

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