Synthesis, structures and properties of two complexes based on benzimidazole or benzothiazole ligand

被引：0
|
作者：
Zhongqiang Zhang
Di Di
Jingshuo Zhai
Lili Wu
Qinlei Zhu
Yanqing Xu
Rudan Huang
机构：
[1] Beijing Institute of Technology,Key Laboratory of Cluster Science, Ministry of Education, School of Chemistry
[2] Hengshui University,Department of Applied Chemistry
来源：
Chemical Research in Chinese Universities | 2014年 / 30卷
关键词：
Chemical synthesis; Crystal structure; Luminescence property; Magnetic property;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Two complexes, Co(Hbim)2(NCS)2(Hbim=benzimidazole)(1) and [Cu(Hbzt)SCN]n(Hbzt=benzothiazole) (2) were synthesized by the same synthesis method and characterized by elemental analysis, infrared spectroscopy(IR), thermogravimetric analysis(TGA), X-ray powder diffraction(XRPD) and single-crystal X-ray diffraction. The results from the single-crystal X-ray diffraction indicate that complex 1 is zero-dimensional(0D) framework and complex 2 is 2-dimensional(2D) framework. In complex 2, the 3-dimensional(3D) supermolecular architecture was built up by means of π-π stacking interaction, and two helical chains existed in its structure. The luminescence properties and the magnetic properties of the two complexes were investigated.
引用
收藏
页码：185 / 189
页数：4
相关论文
共 50 条
  • [1] Synthesis, Structures and Properties of Two Complexes Based on Benzimidazole or Benzothiazole Ligand
    Zhang Zhongqiang
    Di Di
    Zhai Jingshuo
    Wu Lili
    Zhu Qinlei
    Xu Yanqing
    Huang Rudan
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2014, 30 (02) : 185 - 189
  • [2] Transition metal complexes of a benzimidazole ligand containing two heptyl chains: Synthesis, crystal structures, photophysical and thermal properties
    Kirpik, Hilal
    Kose, Muhammet
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1200
  • [3] Synthesis, characterization, and antimicrobial properties of two Cu(II) complexes derived from a benzimidazole ligand
    Kose, Muhammet
    JOURNAL OF COORDINATION CHEMISTRY, 2014, 67 (14) : 2377 - 2392
  • [4] Synthesis, Crystal Structures and Photoluminescent Properties of Two Zinc(II) Complexes Based on Tetrafluoroterephthalate Ligand
    Jia Xiao-Yan
    Cheng Mei-Ling
    Liu Qi
    Hong Jian
    Chen Lin-Ti
    Bao Jin-Ting
    Li Zhan-Feng
    Ji Yun-Zhou
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2013, 29 (09) : 1999 - 2006
  • [5] Two Zn(II) complexes based on bis(benzimidazole) and different dicarboxylate anions: synthesis, structures, and fluorescent properties
    Wu, Zhengwei
    Gao, Wei
    Zhang, Jiaqi
    Lv, Yue
    Fei, Cailing
    Wu, Huilu
    JOURNAL OF COORDINATION CHEMISTRY, 2024, 77 (9-10) : 991 - 1002
  • [6] Synthesis, Structures and Properties of Two Cd(II) Complexes Constructed from Ferrocene-based Carboxylate and Benzimidazole-based Ligands
    Li Zifeng
    Mei Guangjian
    Yue Chun
    Li Gang
    Wang Juan
    Qi Ruobing
    Lan Meng
    ACTA CHIMICA SINICA, 2009, 67 (09) : 1026 - 1031
  • [7] Two silver(I) complexes based on dicarboxylate and flexible bis(benzimidazole) ligands: synthesis, crystal structures, sensing and photocatalytic properties
    Hui Zhu
    Dong Liu
    Yue-Hua Li
    Guang-Hua Cui
    Transition Metal Chemistry, 2020, 45 : 19 - 29
  • [8] Two silver(I) complexes based on dicarboxylate and flexible bis(benzimidazole) ligands: synthesis, crystal structures, sensing and photocatalytic properties
    Zhu, Hui
    Liu, Dong
    Li, Yue-Hua
    Cui, Guang-Hua
    TRANSITION METAL CHEMISTRY, 2020, 45 (01) : 19 - 29
  • [9] Synthesis, crystal structures and properties of two copper (II) complexes with pyridazine derivative ligand
    Li, Xiu-rong
    Zhang, Zhi-hui
    Liu, Xiu-feng
    Gao, Hong
    Zhang, Xiang-nan
    Fan, Zhi-jin
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2008, 38 (10) : 781 - 786
  • [10] Synthesis, crystal structures, and magnetic properties of two heterobinuclear complexes with a dissymmetrical oxamidate ligand
    Liu, B. L.
    Wang, Y. X.
    Li, G. P.
    Tao, R. J.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2013, 39 (01) : 119 - 125
12345