Crystal structure of a tantal cluster with tetraphenylborate-anion: [Ta6Br12(H2O)6](BPh4)2·4H2O

被引：0
|
作者：
A. V. Anyushin
M. N. Sokolov
E. V. Peresypkina
V. P. Fedin
机构：
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Novosibirsk State University,undefined
来源：
Journal of Structural Chemistry | 2013年 / 54卷
关键词：
tantalum; bromine; cluster; X-ray structure; hydrogen bonds;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The crystal structure of the [Ta6Br12(H2O)6](BPh4)2·4H2O salt (1), obtained from Ta6Br14·7H2O and NaBPh4, is determined by X-ray crystallographic analysis. The structure contains a network of hydrogen bonds, which organizes the cluster cations into layers.
引用
收藏
页码：454 / 458
页数：4
相关论文
共 50 条
  • [1] Crystal structure of a tantal cluster with tetraphenylborate-anion: [Ta6Br12(H2O)6](BPh4)2•4H2O
    Anyushin, A. V.
    Sokolov, M. N.
    Peresypkina, E. V.
    Fedin, V. P.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2013, 54 (02) : 454 - 458
  • [2] The cocrystallization of the cubic [Ta6Br12(H2O)6][CuBr2X2]•10H2O and triclinic [Ta6Br12(H2O)6]X2•trans-[Ta6Br12(OH)4(H2O)2]•18H2O (X = Cl, Br, NO3) phases with the coexistence of [Ta6Br12]2+ and [Ta6Br12]4+ in the latter
    Vojnovic, M
    Brnicevic, N
    Basic, I
    Planinic, P
    Giester, G
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2002, 628 (02): : 401 - 408
  • [3] Synthesis, crystal structure, spectroscopic and thermal properties of [Et4N][Ta6Br12(H2O)6]Br4 • 4H2O (Et = ethyl)-A new compound with the paramagnetic [Ta6Br12]3+ cluster core
    Peric, Berislav
    Jozic, Drazan
    Planinic, Pavica
    Brnicevic, Nevenka
    Giester, Gerald
    JOURNAL OF SOLID STATE CHEMISTRY, 2009, 182 (09) : 2443 - 2450
  • [4] Synthesis and crystal structure of [Ni(H2O)6][Ni(H2O)2(C4H2O4)]•4H2O
    Zheng, YQ
    Kong, ZP
    JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (11) : 967 - 973
  • [5] Synthesis and crystal structure of [Ni(H2O)6]Cl2(C6H12N4)2 • 4H2O
    Kokunov, YV
    Khmelevskaya, LV
    Gorbunova, YE
    Mikhailov, YN
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2002, 47 (10) : 1463 - 1466
  • [6] Synthesis and crystal structure of [Ni(H2O)6]Cl2 (C6H12N4)2 · 4H2O
    Kokunov, Yu.V.
    Khmelevskaya, L.V.
    Gorbunova, Yu.E.
    Mikhajlov, Yu.N.
    1600, MAIK Nauka (47):
  • [7] Crystal structure of dodeca-μ-bromo-hexaaqua-1κO,2κO,3κO,4κO,5κO,6κO-octahedro -hexatantalum tetrabromozinkate dodecahydrate, [Ta6Br12(H2O)6][ZnBr4]•12H2O
    Vojnovic, M
    Basic, I
    Brnicevic, N
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 1999, 214 (04): : 435 - 436
  • [8] Structure of an I-•(H2O)6 anion cluster in a 3D anion crystal host [I•(H2O)6Fe(CN)6•H2O]4-
    Wen, D
    Yan, OY
    Song, HB
    Liao, DZ
    Jiang, ZH
    Yan, SP
    Cheng, P
    INORGANIC CHEMISTRY, 2006, 45 (03) : 1168 - 1172
  • [9] Crystal structure of hexaaquacobalt(II) dibromide bis(hexamethylenetetramine) tetrahydrate, [(H2O)6Co]Br2 • 2(C6H12N4) • 4H2O
    Hu, ML
    Fang, LP
    Cheng, YQ
    Jin, ZM
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2002, 217 (01): : 121 - 122
  • [10] Crystal structure of Cs[Gd(H2O)4Re6Te8(CN)6]·4H2O
    M. S. Tarasenko
    N. G. Naumov
    A. V. Virovets
    S. -J. Kim
    V. E. Fedorov
    Journal of Structural Chemistry, 2008, 49 : 1128 - 1131
12345