Relativistic effects in homogeneous gold catalysis

被引：0
|
作者：
David J. Gorin
F. Dean Toste
机构：
[1] University of California at Berkeley,Department of Chemistry
[2] Berkeley,undefined
[3] California 94720,undefined
[4] USA,undefined
来源：
Nature | 2007年 / 446卷
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摘要：
Transition metal catalysts containing gold, especially cationic phosphine-gold(I) complexes, are emerging as powerful catalysts for a growing number of synthetic transformations. Theoretical studies on gold, particularly relativistic effects, can provide a framework for rationalizing the observed reactivity of these catalysts. David Gorin and F. Dean Toste draw on experimental and computational data to present our current understanding of homogeneous gold catalysis.
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页码：395 / 403
页数：8
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