Catalysis by hydrogen carbonate and silicate anions of the oxidation of diethyl sulfide with hydrogen peroxide in aqueous and aqueous-alcoholic media

被引：0
|
作者：
Lobachev V.L. [1 ]
Savelova V.A. [1 ]
Prokop'eva T.M. [1 ]
机构：
[1] L. M. Litvinenko Inst. Phys. O., Natl. Academy of Sciences of Ukraine
来源：
Theoretical and Experimental Chemistry | 2004年 / 40卷 / 3期
关键词：
catalysis; diethyl sulfide; kinetics; mechanism; oxidation;
D O I：
10.1023/B:THEC.0000036211.45290.66
中图分类号：
学科分类号：
摘要：
The kinetics of the oxidation of diethyl sulfide (Et 2S) with hydrogen peroxide, catalyzed by hydrogen carbonate and silicate anions, agree with the assumption that peroxymonocarbonate (HCO - 4) and peroxymonosilicate (HSiO - 4) anions are formed as intermediates. The rate of reaction of Et 2S with HCO - 4 is about 100 times as fast as with H 2O 2. Transfer to aqueous-alcoholic solutions leads to an increase in the solubility of Et 2S while retaining the catalytic effects.
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页码：161 / 166
页数：5
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