New metal complex systems as electrode active components of ion selective electrode membranes

被引：0
|
作者：
M. Yu. Nemilova
N. V. Shvedene
O. V. Mikhalev
I. V. Fedyanin
D. B. Shpakovsky
机构：
[1] Moscow State University,Nesmeyanov Institute of Organoelement Compounds
[2] Russian Academy of Sciences,undefined
来源：
Russian Journal of Coordination Chemistry | 2017年 / 43卷
关键词：
donor–acceptor 3; -transition metal complexes; -4-pyridylbenzamide; -(5-quinolinyl)-3,5-dinitrobenzamide; active components of ion selective electrode (ISE) membranes; thiocyanate-selective electrodes;
D O I：
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学科分类号：
摘要：
New donor-acceptor 3d-transition metal complexes were synthesized and the cobalt and nickel complexes were studied by X-ray diffraction; CIF files CCDC no. 1516693 (III(Ni)) and 1516694 (III(Co)). The crystal structure details of the reactants were discussed. The proposed compounds were tested as the active components of ion selective electrode membranes for determination of thiocyanate ions. The selectivity of the SCN-SE with metal complex-based membranes depends on the ligand structure and the central metal ion type. The proposed electrode is suitable for determination of thiocyanate ions in the presence of sulfate, chloride, nitrate, nitrite, bromide, and iodide ions.
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页码：736 / 744
页数：8
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