Thermodynamics of Ternary Complex Formation of Copper(II) and Nickel Iminodiacetates with Histidine in Solution

被引：0
|
作者：
Dmitrii Pyreu
Julia Bedenko
机构：
[1] Ivanovo State University,Department of Inorganic and Analytic Chemistry
来源：
Journal of Solution Chemistry | 2017年 / 46卷
关键词：
Mixed-ligand complex formation; Calorimetry; Metal(II) iminodiacetate; Histidine; Denticity;
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摘要：
Calorimetric, potentiometric and spectrophotometric studies on the mixed–ligand complexes of copper(II) with nickel iminodiacetates (Ida) and histidine (His) have been carried out in aqueous solution at 298.15 K and ionic strength I = 0.5 mol·dm−3 (KNO3). The thermodynamic parameters of formation of various mixed complexes have been determined. The probable coordination modes of the complexone and histidine residues in the mixed ligand complexes are discussed.
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页码：633 / 642
页数：9
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