Thermoelectric materials based on intermediate phases in the systems formed by chalcogenides of lead and bismuth

被引：3
|
作者：
Shelimova L.E. [1 ]
Karpinskii O.G. [1 ]
Konstantinov P.P. [2 ]
Avilov E.S. [1 ]
Kretova M.A. [1 ]
Nikhezina I.Y. [1 ]
Zemskov V.S. [1 ]
机构：
[1] Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, Moscow
[2] Ioffe Physicotechnical Institute, Russian Academy of Sciences, St. Petersburg
来源：
Inorganic Materials: Applied Research | 2010年 / 1卷 / 02期
关键词：
Crystal structures; Homologous series; Layered chalcogenides; Semiconductors; Systems PbTe-Bi[!sub]2[!/sub]Te [!sub]3[!/sub] and PbSe-Bi2Se3; Ternary compounds; Thermoelectric materials; Thermoelectric properties;
D O I：
10.1134/S2075113310020024
中图分类号：
学科分类号：
摘要：
The crystal structure and the thermoelectric properties of intermediate phases in the quasibinary systems PbTe-Bi2Te3 and PbSe-Bi2Se3 are studied. The compositions of the compounds of the homologous series [PbTe]m[Bi2Te3]n and [(PbSe)5]m[(Bi2Se3)3]n are identified. The significant difference in quantity, composition, and structure of the intermediate phases in the above two systems is shown. The PbTe-Bi2Te3 system is found to contain a series of tetradymite-like compounds with a trigonal symmetry; the PbSe-Bi2Se3 system is characterized by the formation of compounds with monoclinic lattices of a canizzarite mineral type. A correlation between the behavior of the thermoelectric properties and the crystal structure of the ternary compounds is revealed. The thermoelectric properties of alloys of the solid solutions based on the binary components PbTe, PbSe, and Bi 2Te3 are studied. © Pleiades Publishing, Ltd., 2010.
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页码：83 / 91
页数：8
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