Adduct of Triphenylphosphine Oxide and Sulfuric Acid: Synthesis and Structure

被引:0
|
作者
V. V. Sharutin
I. V. Egorova
T. K. Ivanenko
O. K. Sharutina
A. V. Gerasimenko
机构
[1] Blagoveshchensk State Pedagogical University,
来源
Russian Journal of Coordination Chemistry | 2003年 / 29卷
关键词
Oxide; Hydrogen; Physical Chemistry; Hydrogen Bond; Adduct;
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摘要
Adduct of triphenylphosphine oxide and sulfuric acid was synthesized by reacting arenesulfonic acids with triphenylphosphine oxide (1 : 2) in the presence of the moisture of air. According to the X-ray diffraction data, the phosphorous atom has a distorted tetrahedral coordination. The sulfuric acid molecule is disordered over two sites and is linked with two triphenylphosphine oxide molecules through hydrogen bonds.
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页码:297 / 299
页数:2
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