Efficient cyclohexyl acrylate production by direct addition of acrylic acid and cyclohexene over SBA-15-SO3H

被引：0
|
作者：
Feng Zhou
Jihai Tang
Zhaoyang Fei
Xiaoli Zhou
Xian Chen
Mifen Cui
Xu Qiao
机构：
[1] Nanjing University of Technology,Jiangsu Key Laboratory of Industrial Water
[2] Nanjing University of Technology,Conservation and Emission Reduction, College of Chemistry and Chemical Engineering
来源：
Journal of Porous Materials | 2014年 / 21卷
关键词：
Addition esterification; Cyclohexyl acrylate; Solid acid catalyst; SBA-15-SO; H;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A set of propysulfonic acid modified mesostructured silica materials (SBA-15-SO3H) were prepared by a convenient one-pot co-condensation method. Samples were characterized by XRD, FT-IR, Py-FTIR, N2 adsorption–desorption, elemental analysis and acid–base titration. The catalysts exhibited excellent activities and selectivities for addition esterification of acrylic acid and cyclohexene. The highest catalytic activity (82.8 %) and selectivity (92.6 %) were obtained over SBA-15-SO3H (15 %). The efficient catalytic performance of SBA-15-SO3H (15 %) was attributed to the high surface area, proper mesopore texture and presence of sulfonic acid groups in its structure. SBA-15-SO3H catalyst was easily separated and recycled with high stability.
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页码：149 / 155
页数：6
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