Crystal structure of β′-Zn2V2O7

被引:0
|
作者
T. I. Krasnenko
V. G. Zubkov
A. P. Tyutyunnik
L. V. Zolotukhina
E. F. Vasyutinskaya
机构
[1] Russian Academy of Sciences,Institute of Solid State Chemistry, Ural Division
来源
Crystallography Reports | 2003年 / 48卷
关键词
Zinc; Crystal Structure; Comparative Analysis; Diffraction Data; Cell Parameter;
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摘要
The crystal structure of the high-temperature modification of zinc pyrovanadate, namely, β′-Zn2V2O7, is refined by the full-profile Rietveld method (GSAS) using the high-temperature X-ray diffraction data. The crystals are monoclinic (space group C2/m, Z = 2); the unit cell parameters are as follows: a = 6.9324(2) Å, b = 8.4394(2) Å, c = 5.0326(1) Å, and β = 108.272(2)°. Comparative analysis of the crystal structures of β′-Zn2V2O7, β-Mn2V2O7, and Cd2V2O7 is performed.
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页码:35 / 38
页数:3
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