X-ray diffraction studies oncis-[Ru(bpy)2(PMe3)Cl+][ClO4−] andcis-[Ru(bpy)2{PMe2(o-tol)}Cl+][ClO4−]; two ordered structures in thecis-bis(bipyridyl)chloro(phosphine)-ruthenium(II) series

被引：0
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作者：
Melvyn Rowen Churchill
Lynn M. Krajkowski
My Hang Vo Huynh
Kenneth J. Takeuchi
机构：
[1] University at Buffalo,Department of Chemistry
[2] State University of New York,undefined
来源：
Journal of Chemical Crystallography | 1997年 / 27卷
关键词：
Ruthenium(II) complex; trimethylphosphine; dimethyl(; -tolyl)phosphine; bipyridyl; crystal structure; hydrogen bonding;
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摘要：
The complexcis-[Ru(bpy)2(PMe3)Cl+][ClO4−] crystallizes in space group P21/c andcis-[Ru(bpy)2{PMe2(o-tol)]Cl+][ClO4−] crystallizes in space group\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$P\bar 1$$ \end{document}; each is present as a racemate and neither structure suffers from disorder. The Ru−PMe2(o-tol) bond length of 2.324(2)Å is slightly longer than the simple Ru−PMe3 bond length of 2.310(2) Å.
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页码：589 / 597
页数：8
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