Synthesis, crystal, and molecular structure of the solvated complex [MoO2(L)] · DMF (L2− = 2-[N-(2-hydroxynaphthylidene)amino]propane-1,2,3-triol anion)

被引：0

作者：

V. S. Sergienko

V. L. Abramenko

V. I. Sokol

机构：

[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry

[2] Dal’ East Ukrainian National University,undefined

来源：

Russian Journal of Inorganic Chemistry | 2013年 / 58卷

关键词：

Aromatic Aldehyde; Triol; Trans Position; Bidentate Function; Lemon Yellow;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A new dioxomolybdenum(VI) complex, [MoO2(L)] · DMF, where L2− = 2-[N-(2-hydroxynaphthylidene)amino]propane-1,2,3-triol, has been synthesized. Its structure has been determined by X-ray diffraction analysis. The Mo atom is octahedrally coordinated by two oxo ligands that are in cis-positions with respect to each other, two oxygen atoms, the nitrogen atom of the tridentate bis(chelate) ligand L, and the DMF oxygen atom.

引用

页码：1047 / 1051

页数：4

共 50 条

[1] Synthesis, crystal, and molecular structure of the solvated complex [MoO2(L)] • DMF (L2-=2-[N-(2-hydroxynaphthylidene)amino]propane-1,2,3-triol anion)
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[2] Synthesis and Crystal and Molecular Structure of the Solvated Complex [MoO2(L) · C5H5N], Where L2– Is the 2-[N-(2-Hydroxynaphthalidene)amino]propane-1,2,3-Triol Anion
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[3] Synthesis and Crystal and Molecular Structure of the Solvated Complex [MoO2(L) • C5H5N], WhereL2-Is the 2-[N-(2-Hydroxynaphthalidene)amino]propane-1,2,3-Triol Anion
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[6] Intracomplex Dioxomolybdenum(VI) Compounds with Alcoholimines of Aromatic o-Hydroxyaldehydes. Crystal Structure of 2-Hydroxynaphthylidene Monoethanolimine (H2L) and Solvated Complex [MoO2(L) · C5H5N]
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[7] Intracomplex Dioxomolybdenum(VI) Compounds with Alcoholimines of Aromatic o-Hydroxyaldehydes. Crystal Structure of 2-Hydroxynaphthylidene Monoethanolimine (H2L) and Solvated Complex [MoO2(L) Greek ano teleia C5H5N]
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[8] Easy access to derivatives of 2-(hydroxymethyl)propane-1,2,3-triol (isoerythritol) with up to four separately addressable functionalities
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