Studying the Three-Phase Hydrogenation of Nitrobenzene to Aniline in the Presense of a Ruthenium Catalyst

被引：3
|
作者：
Doluda V.Y. [1 ]
Filatova A.E. [1 ]
Sul’man E.M. [1 ]
Matveeva V.G. [1 ,2 ]
Mikhailov S.P. [2 ]
Sidorov A.I. [1 ]
Kosivtsov Y.Y. [1 ]
机构：
[1] Tver State Technical University, Tver
[2] Tver State University, Tver
来源：
Catalysis in Industry | 2018年 / 10卷 / 4期
基金：
俄罗斯基础研究基金会;
关键词：
aniline; hypercrosslinked polystyrene; nitrobenzene; ruthenium; three-phase hydrogenation;
D O I：
10.1134/S2070050418040049
中图分类号：
学科分类号：
摘要：
Abstract: The catalytic hydrogenation of nitrobenzene (NB) is an important technological stage in the production of aniline (AN). The catalytic behavior of hypercrosslinked polystyrene based ruthenium catalyst 3%Ru/MN270 in the three-phase hydrogenation of NB to AN is considered in this work. The following parameters are varied: 0.12 to 0.24 mol/L of NB; 1.11 × 10 −4 to 11.12 × 10 −4 mol/L of catalyst; temperatures of 160 to 190°C; and partial hydrogen pressures of 0.113 to 1.013 MPa. The optimum process parameters are determined to ensure 98% selectivity toward aniline with 97% conversion of nitrobenzene. © 2018, Pleiades Publishing, Ltd.
引用
收藏
页码：328 / 334
页数：6
相关论文
共 50 条
  • [1] Studying the Three-Phase Hydrogenation of Nitrobenzene to Aniline in the Presence of a Ruthenium Catalyst
    Doluda, V. Yu
    Filatova, A. E.
    Sulman, E. M.
    Matveeva, V. G.
    Mikhailov, S. P.
    Sidorov, A., I
    Kosivtsov, Yu Yu
    CATALYSIS IN INDUSTRY, 2019, 11 (02) : 147 - 153
  • [2] Studying the Three-Phase Hydrogenation of Nitrobenzene to Aniline in the Presence of a Ruthenium Catalyst
    V. Yu. Doluda
    A. E. Filatova
    E. M. Sulman
    V. G. Matveeva
    S. P. Mikhailov
    A. I. Sidorov
    Yu. Yu. Kosivtsov
    Catalysis in Industry, 2019, 11 : 147 - 153
  • [3] KINETICS OF HYDROGENATION OF NITROBENZENE TO ANILINE ON A COPPER CATALYST
    PETROV, LA
    KIRKOV, NV
    SHOPOV, DM
    KINETICS AND CATALYSIS, 1985, 26 (04) : 775 - 779
  • [4] Vapor Phase Hydrogenation of Nitrobenzene to Aniline Over Carbon Supported Ruthenium Catalysts
    Srikanth, Chakravartula S.
    Kumar, Vanama Pavan
    Viswanadham, Balaga
    Srikanth, Amirineni
    Chary, Komandur V. R.
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2015, 15 (07) : 5403 - 5409
  • [5] KINETICS OF THE HYDROGENATION OF NITROBENZENE TO ANILINE IN LIQUID-PHASE
    TUREK, F
    GEIKE, R
    CHEMISCHE TECHNIK, 1981, 33 (01): : 24 - 28
  • [6] Kinetics of the Hydrogenation of Nitrobenzene to Aniline in Liquid Phase.
    Turek, Fritz
    Geike, Rainer
    Chemische Technik (Leipzig), 1981, 33 (01): : 24 - 28
  • [7] Hydrogen transfer hydrogenation of nitrobenzene to aniline with Ru(acac)3 as the catalyst
    Wang, Wei
    Zhang, Long
    RESEARCH ON CHEMICAL INTERMEDIATES, 2014, 40 (08) : 3109 - 3118
  • [8] CATALYST REGENERATION REGIMES EFFICIENCY ANALYSIS IN ANILINE PRODUCTION BY NITROBENZENE HYDROGENATION
    BABKOVA, PB
    KHIMICHESKAYA PROMYSHLENNOST, 1990, (03): : 142 - 143
  • [9] The application of an alumina-supported Ni catalyst for the hydrogenation of nitrobenzene to aniline
    Mccullagh, A. M.
    Davidson, A. L.
    Ballas, C. E.
    How, C.
    Maclaren, D. A.
    Boulho, C.
    Brennan, C.
    Lennon, D.
    CATALYSIS TODAY, 2024, 442
  • [10] Selectivity enhancement by catalyst deactivation in three-phase hydrogenation of nerol
    Mäki-Arvela, P
    Kumar, N
    Nasir, A
    Salmi, T
    Murzin, DY
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (25) : 9376 - 9383
12345