Conditioning of Palladium-on-carbon (Pd/C) for Uniform Cinchonidine Modification to Perform Highly Enantioselective Hydrogenation

被引：0
|
作者：
Tae Yeon Kim
Mai Yokota
Takayuki Uchida
Takashi Sugimura
机构：
[1] University of Hyogo,Graduate School of Material Science
来源：
Catalysis Letters | 2009年 / 131卷
关键词：
Enantioselectivity; Hydrogenation; Pd/C; Pretreatment; Carbon texture;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Cinchonidine (CD)-modified palladium catalyst gave the high product ee when a commercial wet Pd/C was used after the co-evaporation pretreatment. The improvement in the ee was attributed to removal of water from a specific Pd/C interior. The use of a water-soluble CD·HCl salt resulted in the high ee without pretreatment.
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页码：279 / 284
页数：5
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