Saturated vapor pressures and enthalpies of evaporation of esters of glycerol and lower carboxylic acids

被引：0
|
作者：
A. S. Maslakova
E. L. Krasnykh
S. V. Levanova
机构：
[1] Samara State Technical University,
来源：
Russian Journal of Physical Chemistry A | 2010年 / 84卷
关键词：
Enthalpy; Retention Index; Saturate Vapor Pressure; Hexanoate; Butanoate;
D O I：
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学科分类号：
摘要：
Saturated vapor pressures and enthalpies of evaporation of trisubstituted esters of glycerol and carboxylic acids C1–C5 with normal and branched structure were determined by the transpiration method in the temperature range of 300–371 K. Dependences of enthalpies of evaporation on the number of carbon atoms in a molecule and on the retention indices are established. Prognostic possibilities of existing calculation schemes are analyzed for compounds with three carboxyl groups in a molecule.
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页码：163 / 168
页数：5
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