2-(diphenylphosphinylmethoxy)aniline: Synthesis, vibrational spectra, and crystal structure

被引：0
|
作者：
L. Kh. Minacheva
I. S. Ivanova
V. E. Baulin
E. N. Pyatova
V. S. Sergienko
A. Yu. Tsivadze
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[2] Russian Academy of Sciences,Institute of Physiologically Active Substances
[3] Russian Academy of Sciences,Frumkin Institute of Physical Chemistry and Electrochemistry
来源：
Russian Journal of Inorganic Chemistry | 2009年 / 54卷
关键词：
Aniline; Vibrational Spectrum; Phosphoryl; Independent Molecule; Cesium Carbonate;
D O I：
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摘要：
The synthesis, vibrational spectra, and X-ray diffraction analysis results for 2-(diphenylphosphinylmethoxy) aniline, 2-[(C6H5)2P(O)OCH2]C6H4NH2(I), are described. The crystals are monoclinic: a = 18.4515(17) Å, b = 10.5421(12) Å, c = 17.897(2) Å, β = 104.479(8)°, V = 3370.7(6) Å3, Z = 8, space group P21/c, R = 0.0546 for 1770 reflections with I > 2σ(I). The unit cell contains two crystallographically independent molecules Ia and Ib joined by an N-H …O hydrogen bond between a hydrogen atom of the amino group of aniline in molecule Ia (Ib) and the phosphoryl oxygen atom of molecule Ib (Ia) (O…H 2.18 and 2.19 Å, N…O, 2.979(5) and 3.000(5) Å; NHO angle, 154° and 157°).
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页码：1571 / 1576
页数：5
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