Catalytic C-phenylation of methyl acrylate with tetraphenylantimony(v) halides and carboxylates

被引：0
|
作者：
A. V. Gushchin
E. V. Grunova
D. V. Moiseev
O. S. Morozov
A. S. Shavyrin
V. A. Dodonov
机构：
[1] N. I. Lobachevsky State University of Nizhnii Novgorod,G. A. Razuvaev Institute of Organometallic Chemistry
[2] Russian Academy of Sciences,undefined
来源：
Russian Chemical Bulletin | 2003年 / 52卷
关键词：
phenylation; methyl acrylate; tetraphenylantimony complexes; palladium compounds; Heck reaction;
D O I：
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学科分类号：
摘要：
Catalytic C-phenylation of methyl acrylate to methyl cinnamate with the Ph4SbX complexes (X = F, Cl, Br, OH, OAc, O2CEt) in the presence of the palladium compounds PdCl2, Pd(OAc)2, Pd2(dba)3, Pd(Ph3P)2Cl2, and Pd(dppf)Cl2 (dba is dibenzylideneacetone and dppf is bis(diphenylphosphinoferrocene)) was studied in organic solvents (MeCN, THF, DMF, MeOH, and AcOH). The highest yield of methyl cinnamate (73% based on the starting organometallic compound) was obtained for the Ph4SbCl—PdCl2 (1 : 0.04) system in acetonitrile.
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页码：1376 / 1379
页数：3
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