Effect of Chlorine Released during Hydrodechlorination of Chlorobenzene over Pd, Pt and Rh Supported Catalysts

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作者
José Luis Benitez
Gloria Del Angel
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来源
Reaction Kinetics and Catalysis Letters | 2000年 / 70卷
关键词
Chlorobenzene; hydrodechlorination; dispersion effect; support effect; Pd/C; Rh/C; Pt/C;
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摘要
Chlorobenzene hydrodechlorination in liquid phase has been studied. Chlorine released during the reaction inhibits conversion in large metallic particles. It was found comparing the behavior of Pd/SiO2, Pd/Al2O3 and Pd/C catalysts that the support plays the role of a chlorine trap. The activity for Pt, Rh and Pd at similar dispersions corresponds to the chlorine adsorption affinity of the metals.
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页码:67 / 72
页数:5
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