Synthesis and properties of nonlinear optical polymers based on poly(ether imides) for electrooptical devices

被引：0
|
作者：
Hyung-Jong Lee
Myung-Hyun Lee
Min-Cheol Oh
Seon Gyu Han
机构：
[1] Telecommunication Basic Research Lab. Electronics and Telecommunications Research Institute,
[2] 161 Kajong-Dong,undefined
[3] Yusong-Gu,undefined
[4] Taejon 305-600,undefined
[5] Korea,undefined
来源：
Polymer Bulletin | 1999年 / 42卷
关键词：
Thermal Stability; Glass Transition; Glass Transition Temperature; Imide; Spin Coating;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
: Nonlinear optical poly(ether imides) with an adequate thermal stability has been synthesized by direct coupling of hydroxy poly(ether imides) and NLO chromophores with a quantitative yield. The resultant amorphous NLO poly(ether imides) exhibited good solubility in common organic solvents, providing optical-quality thin films by spin coating. The glass transition temperatures of the polymers are at around 180 °C. The electrooptic coefficients (r33, @1.3μm) of PEI-DR1 was 12.3 pm/V with an electrical poling field of 100 V/μm and it decayed about 10 % over 10 months at 90 °C under atmospheric conditions.
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页码：403 / 409
页数：6
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