New cage-like metallasiloxane containing FeIII ions in different coordination spheres

被引：0
|
作者：
A. N. Bilyachenko
A. A. Korlyukov
M. M. Levitskii
M. Yu. Antipin
B. G. Zavin
机构：
[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
来源：
Russian Chemical Bulletin | 2007年 / 56卷
关键词：
cage-like metallasiloxanes; X-ray diffraction study;
D O I：
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中图分类号：
学科分类号：
摘要：
The first cage-like ferrophenyl siloxane containing FeIII ions in different coordination spheres (four iron ions have a trigonal-bipyramidal coordination and two iron ions have a distorted octahedral coordination) was synthesized by the exchange reaction of sodium phenylsilanolate with FeIII chloride. An exotic lantern-like structure is formed with the involvement of two metal oxide fragments Fe—O—Fe. The structure of this compound was established by X-ray diffraction.
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页码：543 / 545
页数：2
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