Valence control of ce Ions in cerium-substituted yttrium iron garnet

被引：0
|
作者：
Song Fengbing
Li Qiang
Zhong Zhifeng
机构：
[1] Tsinghua University,Department of Chemistry
来源：
Journal of Wuhan University of Technology-Mater. Sci. Ed. | 2005年 / 20卷 / 1期
关键词：
cerium-substituted yttrium iron garnet; coprecipitation; valence control; Ce;
D O I：
10.1007/BF02870861
中图分类号：
学科分类号：
摘要：
Cerium-substituted yttrium iron garnet (CexY3−xFe5O12, Ce: YIG) was prepared via coprecipitation. The structure, morphology, valence state and constituent of Ce ions were investigated respectively. X-ray powder diffraction (XRD) analysis shows that Ce: YIG was of single cubic YIG phase. The result of X-ray photoelectron spectroscopy (XPS) indicates the Ce ions in Ce: YIG were in the state of trivalence. Scanning electron microscope (SEM) demonstrates the conglobation of Ce: YIG particles about 0.2μm scale. The magnetic properties were studied by a vibrating sample magnetometer (VSM) and the result exhibits that substitution of Ce3+ changes the magnetic parameters of YIG. The effects of doping content of Ce ions and synthesis temperature on valence control were discussed in detail.
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页码：6 / 8
页数：2
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