Measurement and correlation of solubility of xylitol in binary water+ethanol solvent mixtures between 278.00 K and 323.00K

被引:0
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作者
Zhanzhong Wang
Qian Wang
Xiangshan Liu
Wenzhi Fang
Yan Li
Huazhi Xiao
机构
[1] Tianjin University,School of Chemical Engineering and Technology
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关键词
Xylitol; Solubility; Measurement; Correlation; Thermodynamic Properties;
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摘要
The solubility of xylitol in ethanol+water solvent mixtures was measured at temperatures ranging from 278.00 K to 323.00 K at atmospheric pressure by using a laser technique. The results of these measurements were correlated by the combined nearly ideal binary solvent CNIBS/Redlich-Kister equation. The experimental solubility and correlation equation in this work can be used as essential data and models in the purification process of xylitol. The variant 2 in the CNIBS/R-K models was confirmed to be more adaptable to predict solubility of xylitol in binary ethanol +water system. Using the experimentally measured solubilities, the thermodynamic properties of dissolution of xylitol, such as Gibbs energy, molar enthalpy of dissolution, and molar entropy of dissolution, were calculated.
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页码:931 / 936
页数:5
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