Simplified Model for the Critical Thermal-Conductivity Enhancement in Molecular Fluids

被引:0
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作者
R. A. Perkins
J. V. Sengers
I. M. Abdulagatov
M. L. Huber
机构
[1] National Institute of Standards and Technology,Applied Chemicals and Materials Division
[2] University of Maryland,Institute for Physical Science and Technology
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关键词
Acentric factor; Correlation length; Corresponding states; Critical amplitudes; Critical dynamics; Mode-coupling theory; Thermal conductivity; Thermal diffusivity;
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摘要
This paper reviews the available information for the thermal-conductivity enhancement. This enhancement can be represented by a simplified solution of the mode-coupling theory of critical dynamics with two critical amplitudes and one cutoff wave number as fluid-specific parameters. Using corresponding states, these fluid-specific parameters are correlated in terms of their dependence on the acentric factor. A universal representation of the critical enhancement of the thermal conductivity for a large number of molecular fluids is presented.
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页码:191 / 212
页数:21
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