Three New Cadmium Complexes Based on 3-Nitrophthalic Acid: Syntheses, Crystal Structures and Fluorescent Properties

被引：0
|
作者：
Zhen-Xiu Si
Wei Xu
机构：
[1] Ningbo University,Center of Applied Solid State Chemistry Research
来源：
Journal of Cluster Science | 2016年 / 27卷
关键词：
Metal–organic complexes; 3-Nitrophthalic acid; Crystal structure; Luminescent properties;
D O I：
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中图分类号：
学科分类号：
摘要：
Three metal–organic coordinate complexes based on 3-nitrophthalic acid (H2NPA), namely Cd2(H2O)(OH)2(NPA) (1), Cd2(Im)4(NPA)2 (2) and Cd2(Bim)4(H2O)(NPA)2 (3) (Im = imidazole, Bim = benzimidazole), have been obtained by hydrothermal method and characterized by X-ray single crystal structure determination. Structural analysis reveals that complex 1 exhibits 2D layers constructed by polyhedral aggregates. Complex 2 exhibits a dinuclear cadmium structural unit and assembles by hydrogen bonds into a 2D supramolecular architecture. Complex 3 is assembled by NPA2− into layers of a (3,4)-connected dinodal net topology of (4·52)(4·53·72). The fluorescent properties of complexes 1–3 have been investigated.
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页码：603 / 615
页数：12
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