3,5-Bis(ferrocenylmethylene)-1-methyl-4-methylenepiperidine. Synthesis and some chemical properties

被引：0
|
作者：
E. I. Klimova
M. Martinez Garcia
T. Klimova
L. Ruiz Ramirez
J. M. Mendez Stivalet
N. N. Meleshonkova
机构：
[1] Universidad Nacional Autonoma de Mexico,Facultad de Quimica
[2] Universidad Nacional Autonoma de Mexico,Instituto de Quimica
[3] M. V. Lomonosov Moscow State University,Department of Chemistry
来源：
Russian Chemical Bulletin | 2000年 / 49卷
关键词：
piperidine; triene; cyclodimerization; dimerization; fragmentation; allylic cation; ferrocene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
3,5-Bis(ferrocenylmethylene)-1-methyl-4-methylenepiperidine, a diferrocenyltriene with a fixeds-cisoid conformation of the exocyclic double bonds, was synthesized. On heating, this compound cyclodimerizes according to the [4+2]-cycloaddition scheme; it forms Diels-Alder adducts with azodicarboxylic and maleic acidN-phenylimides. The compound easily cyclodimerizes in the presence of acids by a proton cyclodimerization mechanism to give a spiro cyclodimer. The triene also adds a 3,5-bis(ferrocenylmethylene)-1,4-dimethyl-1-azonia-4-cyclohexyl salt to the terminal methylene group yielding linear and cyclic addition products.
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页码：514 / 519
页数：5
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